Determination of structural features of o-alkyl-s-2-(n, n-dialkylamino) ethylalkylthiophosphonates from their electron ionization mass spectra

T12N4

A.G. Terentyev, Yu.I. Morozik, I.V. Rybal’chenko,
A.V. Dudkin, A.O. Smirnov, G.V. Galyaev

It is believed that information about the molecular structure of highly toxic O-alkyl-S-2-(N,N-dialkylamino) ethylalkylthiophosphonates (V-gases), obtained from their EI mass spectra is too insufficient. In particular, determination of molecular weight and structure of radicals at phosphorus and oxygen atoms causes great difficulties. In this paper, solutions of these problems are proposed.

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