Chemical structure elucidation of gas chromatographic artifact of synthetic cannabinoid N-(1-carbamoyl-2-methylpropyl)-1-(cyclohexylmethyl)-1H-indazol-3-carboxamide by means of high resolution mass spectrometry

T13N4

V.A. Shevyrin

Synthetic cannabinoids are the most popular psychoactive compounds within illegal market. In a course of gas chromatographic determination, some synthetic cannabinoids undergo chemical transformations due to their thermal interaction with chromatographic system. The present paper is devoted to structure elucidation of gas chromatographic artifact formed from synthetic cannabinoid N-(1-carbamoyl-2-methylpropyl)-1-(cyclohexylmethyl)-1H-indazol-3-carboxamide as a result of dehydratation of its terminal carbamoyl moiety. Structure of the artifact was determined by means of high resolution mass spectrometry.

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